Journal
TETRAHEDRON LETTERS
Volume 41, Issue 13, Pages 2129-2132Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00091-5
Keywords
cyclization; acid catalyst; silicon and compound; oxidation
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A benzyldimethylsilyl (BnDMS) group was found to effectively enhance the reactivity of vinylsilanes toward the acid-catalyzed intramolecular addition of a hydroxy group in comparison with a dimethylphenylsilyl group. The BnDMS group of the resultant cyclized products could be easily converted to a hydroxy group by the action of TBAF-H2O2-KHCO3. (C) 2000 Elsevier Science Ltd. All rights reserved.
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