Journal
VIBRATIONAL SPECTROSCOPY
Volume 23, Issue 1, Pages 83-94Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0924-2031(99)00087-9
Keywords
carbon dioxide; IR spectroscopy; matrices; dimers
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New FTIR CO2 high resolution spectra are recorded in argon and nitrogen matrices at 11 K at high dilution. Their evolution with CO2 diffusion at higher temperature is also traced. New observations are discussed in regard to previous works. Even at high dilution (1/10 000), the temperature increase causes appearance of several bands both in argon and nitrogen. Identification of carbon dioxide dimer absorptions is tentatively proposed, (C) 2000 Elsevier Science B.V. All rights reserved.
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