Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 36, Issue 4, Pages 375-408Publisher
SPRINGER
DOI: 10.1023/A:1008079027142
Keywords
calixarenes; crown ethers; azobenzene; ditopic receptors; cation complexation; cation extraction; nuclear wastes; crystal structures; molecular modelling; molecular dynamics
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The association within one molecule of calix[4]arene and crown ether moieties leads to ligands with new complexing properties. In particular, calix[4]arene bis(crown-6) and some of its derivatives have been shown to be highly selective extractants for caesium ions. This review presents the background of the study and the results of crystal structure determinations and molecular modelling calculations performed during the investigation of two molecular families, the bis(crown ether) and the azobenzocrown derivatives of calix[4]arene.
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