Development of highly microporous activated carbon from the alcoholic beverage industry organic by-products

This work has the aim to employ the agave bagasse, a waste from Tequila and Mescal industries, to obtain a product of high commercial value such as activated carbon. The activated carbon production methodology was based on a chemical activation, by using ZnCl2 and H3PO4 as activating agent and agave bagasse as a natural source of carbon. The activation temperature (150-450 degrees C), activation time (0-60 min) and weight ratio of activating agent to precursor (0.2-4) were studied. The produced carbon materials were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and nitrogen physisorption at 196 degrees C. In addition, the activating agent recovery was evaluated. We were able to obtain highly microporous activated carbons with micropore volumes between 0.24 and 1.20 cm(3)/g and a surface area within 300 and 2139 m(2)/g. These results demonstrated the feasibility to treat the industrial wastes of the Tequila and Mescal industries, being this wastes an excellent precursor to produce highly microporous activated carbons that can be processed at low activation temperatures in short times, with the possibility of recycling the activating agent. (C) 2010 Elsevier Ltd. All rights reserved.