4.4 Article

Pyridinium N-(2′-azinyl)aminides:: Regioselective synthesis of 2-alkylaminoazines

Journal

TETRAHEDRON
Volume 56, Issue 16, Pages 2481-2490

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00084-3

Keywords

alkylation; amidines; pyridinium salts; ylids

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The regioselective alkylation of pyridinium-N-(2'-azinil)aminides with alkyl halides under mild conditions is described. The alkylation, combined with a reduction of the N-N bond, allows an easy preparation of 2-alkylaminoazines. (C) 2000 Elsevier Science Ltd. AU rights reserved.

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