☆ 4.4 Article

A new route to α-trifluoromethyl-α,β-unsaturated esters

TETRAHEDRON LETTERS (2000)

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Journal

TETRAHEDRON LETTERS
Volume 41, Issue 16, Pages 2953-2955

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00279-3

Keywords

trifluoromethylation; alpha,beta-unsaturated esters

Categories

Chemistry, Organic

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The treatment of alpha-bromo-alpha,beta-unsaturated esters with FSO2CF2CO2Me and CuI in DMF/HMPA constitutes a new synthetic scheme for the preparation of alpha-trifluoromethyl-alpha,beta-unsaturated esters. (C) 2000 Elsevier Science Ltd. All rights reserved.

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