Journal
TETRAHEDRON
Volume 56, Issue 17, Pages 2655-2664Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00154-X
Keywords
electrochemistry; fluorine and compounds; S(RN)1; indole; purine
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In an effort to prepare new fluorine-containing molecules as analogues of Plant Growth Regulators (PGRs), the indirect electrochemical reduction, by means of an aromatic anion mediator, of perfluoroalkyl halides in the presence of purine and indolyl anions was carried out. The corresponding C-perfluoroalkylated products were obtained by an S(RN)1 mechanism, in moderate to good yields, and biological activity of some of the products was evaluated. (C) 2000 Elsevier Science Ltd. All rights reserved.
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