Journal
TETRAHEDRON LETTERS
Volume 41, Issue 17, Pages 3069-3072Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00337-3
Keywords
trifluoromethanethiosulfonates; trifluorothioacetates; photolysis; (trifluoromethyl)alkanes
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The photolysis of trifluoromethanethiosulfonates (CF3SO2SR) or trifluorothioacetates (CF3COSR) in the presence of alkenes provides (trifluoromethyl)alkanes or beta-sulfanyl (trifluoromethyl)alkanes. The formation of these compounds can be controlled by the nature and the ratio of the reactants. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.
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