Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 104, Issue 16, Pages 3566-3571Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp993623b
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The products of the reaction of laser-ablated red phosphorus and dioxygen have been studied using experiment and theory. The bands at 480.3 and 1273.3 cm(-1), previously attributed to PO3 in the matrix isolation IR experiments, are reassigned to PO3-. Also observed in experiment are PO2, PO2-, P2O, OPOPO, P-4, and higher oxides.
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