Journal
TETRAHEDRON
Volume 56, Issue 18, Pages 2727-2731Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00127-7
Keywords
copper catalysis; conjugate addition; polyfunctional organomagnesium compounds
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Highly functionalized arylmagnesium bromides are readily prepared by an iodine-magnesium exchange reaction. In the presence of catalytic amounts of copper(I) salts and chlorotrimethylsilane, they add to various enones leading to the conjugate addition products in 66-89% yield. (C) 2000 Elsevier Science Ltd. All rights reserved.
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