Journal
PHYSICAL REVIEW LETTERS
Volume 84, Issue 18, Pages 4144-4147Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.84.4144
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Reverse Monte Carlo produced structural models of silver ion conducting glasses and crystals have been investigated by the bond-valence technique. Both absolute ionic conductivity and activation energy can be determined directly from the pathway volume of the structural models, i.e., from the volume fraction of the percolating pathway cluster. This pathway volume-conductivity relation was found to hold fur glassy and crystalline systems with silver ion conductivities differing by more than 11 orders of magnitude. Earlier, less universal rules were rationalized and unified by means of this approach.
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