4.7 Article

Thermal condensation of trinuclear lanthanide butoxides.: Molecular structure of La5 (μ5-O) (μ3-OtBu)4(μ-OtBu)4(OtBu)5

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 3, Issue 5, Pages 218-220

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(00)00051-4

Keywords

lanthanide complexes; oxo complexes; alkoxide complexes; yttrium; crystal structures

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Refluxing of Ln(3)((OBu)-Bu-t)(9)((BuOH)-Bu-t)(2) (Ln=La, Nd, Yb) in toluene led to Ln(5)O((OBu)-Bu-t)(13) which was characterised by X-ray diffraction in the case of lanthanum. Aggregates of higher nuclearity were obtained in similar conditions for yttrium and praseodymium. (C) 2000 Elsevier Science S.A. All rights reserved.

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