Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 3, Issue 5, Pages 251-254Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(00)00061-7
Keywords
cobalt(II) complexes; five-coordinate complexes; crystal structures; quinoxaline complexes
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Reaction of Co(II) perchlorate hexahydrate and anhydrous Co(II) chloride with the ligand 2-(2'-pyridyl)quinoxaline (L) leads to the formation of the novel five- and six-coordinated complexes CoLCl2(DMF) (1) and [CoL2(H2O)(2)](ClO4)(2). H2O 2CH(3)OH (2), correspondingly. The crystal structures of the above complexes show a trigonal bipyramidal geometry around the metal atom for complex 1 and a distorted octahedral geometry for complex 2. (C) 2000 Elsevier Science S.A. All rights reserved.
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