Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 225, Issue 1, Pages 94-104Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1006/jcis.1999.6697
Keywords
iron oxide; goethite; fluoride; proton; hydroxyl, adsorption; coadsorption; H bonds; CD-MUSIC; singly coordinated; doubly coordinated; surface group, surface site, site density
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Metal (hydr)oxides have different types of surface groups. Fluoride ions have been used as a probe to assess the number of surface sites. We have studied the F- adsorption on goethite by measuring the F- and H+ interaction and F- adsorption isotherms. Fluoride ions exchange against singly coordinated surface hydroxyls at low F- concentrations. At higher concentrations also the doubly coordinated OH groups are involved. The replacement of a surface OH- by F- suggests that all F charge (-1) is located at the surface in contrast to oxyanions which have a charge distribution in the interface due to the binding structure in which the anion only partially coordinates with the surface. Analysis of our F- data with the CD-MUSIC approach shows that the formation of the fluoride surface complex is accompanied by a redistribution of charge. This is supposed to be due to a net switch in the H bonding as a result of the change of the type of surface complex from donating (FeOH, FeOH2) to proton accepting (FeF). The modeled redistribution of charge is approximately equivalent with the change of a donating H bond into an accepting H bond. At high F- concentrations precipitation of F-, as for instance FeF3(s), may occur. The rate of formation is catalyzed by the presence of high electrolyte concentrations. (C) 2000 Academic Press.
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