Journal
PHYTOCHEMISTRY
Volume 54, Issue 1, Pages 85-92Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0031-9422(00)00049-2
Keywords
Gentiana makinoi; gentiodelphin; acylated anthocyanin; intramolecular stacking; flower color development; conformational analysis
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To clarify the function of each caffeoyl residue in the diacylated anthocyanin gentiodelphin, a pigment from the blue flower of Gentiana makinoi, two mono-deacyl derivatives were compared for both color development and stability. In neutral solution, 3.5-di-O-beta-D-glucopyranosyl-3'-O-(6-O-caffeoyl-beta-D-glucopyranosyl)delphinidin was both bluer and more stable than 3,3'-di-0-8D-glucopyrannsyl-5-O-(6-O-caffeoyl-beta-D-glucopyranosyl)delphinidin. Conformational analysis of each derivative under acidic conditions revealed only the 3'-O-caffeoylglucopyranosyl derivative to demonstrate intramolecular stacking. Additionally, the acyl residue in the B-ring contributed more to blue color development than that in the A-ring. (C) 2000 Elsevier Science Ltd. All rights reserved.
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