4.7 Article

Synthesis of glycophostones: Cyclic phosphonate analogues of biologically relevant sugars

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 65, Issue 9, Pages 2667-2674

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo991696l

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Analogues of L-fucose, N-acetyl-D-glucosamine, N-acetyl-D-mannosamine, and N-acetyl neuraminic acid in which the anomeric carbon atom was replaced by a phosphonyl group (phostones or cyclic phosphonates) were synthesized by stereocontrolled methods relying on the Abramov reaction.

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