Journal
TETRAHEDRON LETTERS
Volume 41, Issue 19, Pages 3717-3720Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00473-1
Keywords
hydroformylation; rhodium catalysts; biphasic catalysis; Rh-proteins
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A highly efficient and chemoselective biphasic hydroformylation of olefins was accomplished using water soluble complexes formed by the interaction between Rh(CO)(2)(acac) and human serum albumin (HSA), a readily available water soluble protein. A new type of shape-selectivity was observed in the hydroformylation of sterically hindered olefins. (C) 2000 Elsevier Science Ltd. All rights reserved.
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