4.5 Article

Photo-physical characterization of rhodamine 6G in a 2-hydroxyethyl-methacrylate methyl-methacrylate copolymer

Journal

CHEMICAL PHYSICS
Volume 256, Issue 1, Pages 125-136

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S0301-0104(00)00101-4

Keywords

solid-state dye laser material; dye-doped polymer; rhodamine 6G; HEMA-MMA copolymer; fluorescence analysis; adsorption spectra; photo-degradation; saturable absorption; excited-state absorption

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Some photo-physical parameters of 1 x 10(-4) and 5.9 x 10(-4) M samples of rhodamine 6G in a 2-hydroxyethyl-methacrylate methyl-methacrylate copolymer (volume mixture 1:1) are determined and compared with rhodamine 6G in methanol. They include the absorption cross-section and stimulated emission cross-section spectra, the fluorescence quantum distributions, quantum yields and lifetimes. The photo-degradation under steady-state and pulsed excitation is investigated. The saturable absorption behaviour under picosecond laser excitation is studied. (C) 2000 Elsevier Science B.V. All rights reserved.

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