4.6 Article

Hydrodynamic layer thickness of a polybase brush in the presence of salt

Journal

LANGMUIR
Volume 16, Issue 10, Pages 4467-4469

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la991263d

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A grafted weak polyelectrolyte brush has been prepared by the incorporation of one block of a diblock copolymer inside a latex particle. The preformed brush shows a maximum in its hydrodynamic layer thickness radius as a function of added salt. Beyond 0.025 M NaCl, the data can be fitted to the scaling relationship for the salted-brush regime wherein the layer thickness varies as the inverse cubed root of the ionic strength.

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