Journal
ORGANIC LETTERS
Volume 2, Issue 10, Pages 1353-1356Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0055667
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A molecular shuttle containing dodecamethylene units, 4,4'-bipyridinium units, and alpha-cyclodextrin (alpha-CD) has been prepared. Shuttling behavior is solvent and temperature-sensitive and could be controlled by double interactions: hydrophobic interaction between a CD ring and a station and a repulsive interaction between a CD ring and a linker. This is a novel method to control the mobility of a bead in a molecular shuttle.
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