Journal
CHEMICAL PHYSICS LETTERS
Volume 322, Issue 5, Pages 429-438Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(00)00467-X
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The photodissociation of BrCl has been investigated at 235 nm using a two-dimensional photofragment ion imaging technique. Three direct dissociation channels were observed with the quantum yields of Phi[Br(P-2(1/2)) + Cl(P-2(3/2))] = 0.58 +/- 0.05, Phi[Br(P-2(3/2)) + Cl(P-2(1/2))]= 0.16 +/- 0.05, and Phi[Br(P-2(3/2)) + Cl(P-2(3/2))]= 0.26 +/- 0.05, and angular distributions were represented by anisotropy parameters, beta = 1.98 +/- 0.05, - 1.04 +/- 0.05, and 1.88 +/- 0.05 respectively. The results indicate that the 2341 (II0+)-I-3 State plays a key role in the dissociation dynamics after absorbing a photon. Based on the results of BrCl and newly found probe lines for Br atoms, the ionization probability ratios of Cl(P-2(3/2) or P-2(1/2)) to Br(P-2(3/2) or P-2(1/2)) were determined. (C) 2000 Elsevier Science B.V. All rights reserved.
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