Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 147, Issue 6, Pages 2252-2257Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.1393516
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Nucleation and growth mechanism of polypyrrole films was investigated on vapor deposited gold/highly oriented pyrolytic graphite by current-time transient (i-t) measurements and atomic force microscopy. It was found that the nucleation and growth was an instantaneous two-dimensional process before nuclei overlapping and progressive three-dimensional after nuclei overlapping. The polypyrrole structure was observed to be zigzag or screw-type and particle-like for thin and thick films, respectively. (C) 2000 The Electrochemical Society. S0013-4651(99)06-153-4. All rights reserved.
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