Journal
ORGANIC LETTERS
Volume 2, Issue 11, Pages 1621-1624Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0059100
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[GRAPHICS] A general method for the functionalization of Si-Cl terminated carbosilane dendritic molecules via organolithium or organomagnesium reagents is described. Quantitative exchange of the bromine atoms of 4-bromophenyl-functionalized dendrimers affords polylithiated species that are valuable starting materials for further functionalization, e.g., into pyridyl alcohols. The latter were successfully applied as catalyst precursors in a ruthenium-mediated ring-closure metathesis reaction.
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