The fluctuation theorem and Green-Kubo relations

Green-Kubo and Einstein expressions for the transport coefficients of a fluid in a nonequilibrium steady state can be derived using the fluctuation theorem and by assuming the probability distribution of the time-averaged dissipative flux is Gaussian. These expressions are consistent with those obtained using linear response theory and are valid in the linear regime. It is shown that these expressions are, however, not valid in the nonlinear regime where the fluid is driven far from equilibrium. We advance an argument for why these expressions are only valid in the linear response, zero field limit. (C) 2000 American Institute of Physics. [S0021-9606(00)51221-5].