Journal
TETRAHEDRON LETTERS
Volume 41, Issue 24, Pages 4695-4699Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00713-9
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The origin of asymmetric induction in a chiral auxiliary derived from isomannide was probed using a series of eta(6) arene chromium carbonyl complexes. Diastereoselectivity as high as 99% was attainable, and subsequent spectroscopic analysis shed light on the role of pi-pi interactions. (C) 2000 Elsevier Science Ltd, All rights reserved.
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