Journal
TETRAHEDRON LETTERS
Volume 41, Issue 25, Pages 4909-4912Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00717-6
Keywords
supramolecular chemistry; fullerenes; cyclodextrins; electron transfer
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The successive treatment of gamma-cyclodextrin-bicapped C-60 complex (1) with FeCl2 and NaOH in aqueous solution at ambient temperature produces rapidly its C-60(1-) complex in quantitative yield. The C-60(1-) complex formation is quantitative, even in the contact with O-2, if Na2S2O4 is present. Plausible electron transfer mechanism is discussed. (C) 2000 Elsevier Science Ltd. All rights reserved.
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