4.8 Article

A facile construction of the quadranoid skeleton:: Application to the total synthesis of (±)-suberosenone

Journal

ORGANIC LETTERS
Volume 2, Issue 13, Pages 1951-1953

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol0060230

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A tandem free radical cyclization-rearrangement sequence was designed and executed to produce tricyclo[4.3.2.0(1,5)]undecane 7 from cyclopentene 6A in a single operation. The total synthesis of suberosenone was accomplished from 7.

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