Journal
ORGANIC LETTERS
Volume 2, Issue 13, Pages 1855-1857Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0059145
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Treatment of terminal alkynes bearing a remote leaving group with MNR2 (M = Li, Na, K) gives bicyclo[n.3.0]-1-alkenes (n = 3, 4). The tandem cyclization proceeds through a mechanism involving exo-cyclization of an alkynylmetal intermediate and intramolecular C-H insertion of the resulting carbenoid.
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