Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 2, Issue 7, Pages 453-456Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/S1388-2481(00)00055-2
Keywords
electroneutrality; Nernst-Planck; Poisson; Gouy-Chapman; charge density; electric field
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A simple treatment is developed to demonstrate that invoking the electroneutrality assumption to solve electrochemical transport problems is equivalent to invoking the limit of the exact (Nernst-Planck-Poisson) treatment when certain charge-density-related terms become negligibly small. (C) 2000 Elsevier Science S.A. All rights reserved.
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