Journal
APPLIED RADIATION AND ISOTOPES
Volume 53, Issue 1-2, Pages 153-157Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0969-8043(00)00127-5
Keywords
activated carbon; technetium; environmental waters
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The sorption of technetium in pertechnetate form on carbon has been investigated. The sorption is pH dependent with maximal distribution coefficients, K-d, in the order of 10(6) at pH 2-4 for activated carbon with a grain size less than or equal to 100 mu m. The equilibrium time to reach such distribution coefficient was about 5 h at room temperature. The exact mechanisms for the sorption are not fully understood but reduction of Tc by the carbon might be an important process. Technetium can effectively and rapidly (5 l min(-1)) be sorbed from very large volumes (several hundred liters) of environmental waters on commercial cartridge filters impregnated with activated carbon. After incineration, the filters can be analyzed for Tc-99 by conventional methods. (C) 2000 Elsevier Science Ltd. All rights reserved.
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