Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 33, Issue 7, Pages 475-481Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar9702841
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In this Account, we discuss the dynamic features of self-assembled monolayers (SAMs) on both planar and nonplanar substrates. Our focus is on organothiol and organic acid-based monolayers. Results from variable-temperature electrochemical, calorimetric, vibrational, and solid-state NMR spectroscopic measurements lead to a convergent description of SAM dynamics.
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