Journal
CHEMISTRY OF MATERIALS
Volume 12, Issue 7, Pages 1990-1994Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm0002057
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The brucite-like Ca2+/Al3+ layered double hydroxide (LDH), Ca2Al(OH)(6). NO3. 2H(2)O, was synthesized using the coprecipitation method. The dicarboxylate anion 1,4-benzenedicarboxylate can be selectively intercalated into the layered double hydroxide Ca2Al(OH)(6). NO3. 2H(2)O from an aqueous solution containing an equimolar mixture of the 1,2- and 1,4-benzenedicarboxylates. Time-resolved in situ energy-dispersive X-ray diffraction studies of the competitive intercalation reaction reveal that initially both the 1,2- and the 1,4-benzenedicarboxylates are intercalated in the LDH, followed by replacement of the 1,2-benzenedicarboxylate by the 1,4-isomer as the reaction proceeds. The final thermodynamic product is Ca2Al(OH)(6).[1,4-C8H4O4](0.5). xH(2)O.
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