4.4 Article

Applications of the Stell-Hemmer potential to understanding second critical points in real systems

Journal

JOURNAL OF STATISTICAL PHYSICS
Volume 100, Issue 1-2, Pages 97-106

Publisher

KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1018631426614

Keywords

simple liquids; core-softened potentials; liquid-liquid critical point; density anomaly; diffusivity anomaly; liquid water; liquid metals

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We consider the novel properties of the Stell-Hemmer core-softened potentials. First we explore how the theoretically predicted second critical point for these potentials is related to the occurrence of the experimentally observed solid-solid isostructural critical point. We then discuss how this class of potentials can generate anomalies analogous to those found experimentally in liquid water.

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