Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 488, Issue 2, Pages 99-109Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(00)00185-6
Keywords
ITIES; electrodeposition; palladium; nucleation; nanoparticles
Categories
Ask authors/readers for more resources
A model has been developed for diffusion controlled electrodeposition of metallic particles at the interface between two immiscible electrolyte solutions. A rate law was derived for the case where no preferential nucleation sites ate present. Palladium particles were deposited at the water \ 1,2-dichloroethane interface by reduction of aqueous ammonium palladate using butylferrocene in the organic phase as electron donor. Experimental results were in good agreement with the theoretical model derived. The potential dependence of the nucleation rate was found to follow a classical exponential law. (C) 2000 Elsevier Science S.A. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available