4.7 Article

Static dielectric constant of aqueous electrolyte solutions: Is there any dynamic contribution?

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 113, Issue 3, Pages 903-905

Publisher

AIP Publishing
DOI: 10.1063/1.481870

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We investigate the presence of dynamic cross correlation between ionic current and collective dipole moment fluctuations and the contribution of such dynamic cross correlations to the static dielectric constant of electrolyte solutions by means of a series of sufficiently long molecular dynamics simulations of aqueous NaCl and KCl solutions at different concentrations ranging from 0.88 M to 4.5 M. (C) 2000 American Institute of Physics. [S0021-9606(00)51327-0].

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