Journal
PHYSICAL REVIEW LETTERS
Volume 85, Issue 3, Pages 590-593Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.85.590
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The liquid-gas spinodal and the glass transition define ultimate boundaries beyond which substances cannot exist as (stable or metastable) liquids. The relation between these limits is analyzed via computer simulations of a model liquid. The results obtained indicate that the liquid-gas spinodal and the glass transition lines intersect at a finite temperature, implying a glass-gas mechanical instability locus at low temperatures. The glass transition lines obtained by thermodynamic and dynamic criteria agree very well with each other.
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