4.4 Article

Synthetic studies on kinamycin antibiotics: elaboration of a highly oxygenated D-ring

Journal

TETRAHEDRON LETTERS
Volume 41, Issue 30, Pages 5693-5697

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00932-1

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The synthesis of the model compound of kinamycin antibiotics, which possesses correct relative configurations at C(1)-C(4) on the D-ring, is reported. The key steps involve a Diels-Alder reaction of an indenone and a Danishefsky-type diene, and stereoselective construction of a tetraoxygenated D-ring. (C) 2000 Elsevier Science Ltd. All rights reserved.

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