Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 65, Issue 15, Pages 4553-4559Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo000116d
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The synthetic potentialities of cerium(III) chloride are demonstrated by the synthesis of a nine-membered ring heterocycle component of Griseoviridin (3) in optically active form. The key step involves the stereospecific formation of the alpha-carbalkoxy alkenyl sulfide moiety using a combination system of cerium(III) chloride heptahydrate and sodium iodide.
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