Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 65, Issue 15, Pages 4575-4583Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo000182f
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Homo- and cross-coupling involving alkenyl halides have been performed efficiently using an electroassisted nickel-complex catalysis. Valuable product such as conjugated dienes, beta,gamma- or gamma,delta-unsaturated esters, ketones, or nitriles, as well as alkenylated aryl compounds are thus prepared with high yields and high stereoselectivity. Partial isomerization is only observed in a few cases, when the alkenyl halide is involved in a late step of the catalytic cycle. This is the case in the preparation of (Z,Z)-1,3-diene.
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