Journal
PHYSICAL REVIEW B
Volume 62, Issue 6, Pages 3811-3815Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.62.3811
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A new compound with the composition of Sr3Ru2O7F2 has been obtained by fluorination of the double layered Ruddlesden-Popper phase, Sr3Ru2O7 Neutron powder diffraction (NPD) reveals that due to a similar rotation of RuO6 octahedra, the structure of Sr3Ru2O7F2 can be described with the same space group Pban as Sr3Ru2O7 but with a large expansion in the c axis and slight contraction in the ab plane [a=5.4231(4) Angstrom, b=5.4168(4) Angstrom, and c=24.2505(8) Angstrom, 290 K]. The fluorinated ruthenate retains the layer structure: F occupies the interstitial sites in the rock salt layer leaving the double RuO layer intact. NPD at 2 K shows that Sr3Ru2O7F2 is antiferromagnetic, with a G-type ordering of the Ru spins and an ordered moment of mu(z) = 1 mu(B)/Ru along the c direction. Magnetization measurements implies a small ferromagnetic moment below 185 K, which is attributed to canting of the Ru spins from the c axis.
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