Journal
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY
Volume 64, Issue 8, Pages 1751-1753Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1271/bbb.64.1751
Keywords
nitric oxide; nitrite; peroxynitrite; photo-induced catalysis; titanium dioxide
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During a photo-induced catalytic reaction under near UV irradiation to an aqueous suspension of TiO2, about 95% of NO2- was oxidized to NO3-, but NH4+ was not detected, The oxidation was inhibited by the addition of mannitol or under anaerobic conditions. The nitration of I-IPA was observed in the presence of t-buthanol, suggesting the formation of ONOO-. An ESR spectrum gave a triplet signal at g = 2.041, in the presence of NO2-, mannitol, FeSO4, and MGD, indicating the reduction of NO2- to NO.
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