Journal
PURE AND APPLIED CHEMISTRY
Volume 72, Issue 8, Pages 1453-1470Publisher
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/pac200072081453
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This paper presents definitions of concepts related to speciation of elements, more particularly speciation analysis and chemical species. Fractionation is distinguished from speciation analysis, and a general outline of fractionation procedures is given. We propose a categorization of species according to isotopic composition of the element, its oxidation and electronic states, and its complex and molecular structure. Examples are given of methodological approaches used for speciation analysis. A synopsis of the methodology of dynamic speciation analysis is also presented.
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