4.7 Article

Nitrosyl transfer from manganese to iron in tropocoronand complexes

Journal

INORGANIC CHEMISTRY
Volume 39, Issue 16, Pages 3722-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic000360n

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A nitrosyl transfer reaction is described in which the NO ligand from [Mn(NO)(TC-5,5)] quantitatively transfers to [Fe(TC-5,5)] to form [Fe(NO)(TC-5,5)]. The reaction was monitored by in situ IR spectroscopy to reveal data consistent with NO dissociation from Mn prior to interaction with Fe. [GRAPHICS]

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