Journal
TETRAHEDRON LETTERS
Volume 41, Issue 33, Pages 6323-6326Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)00961-8
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A stereocontrolled synthesis of the C15-C27 fragment of laulimalide is described. Key features are a divergent-convergent synthesis from (R)-glycidol, an interesting formation of a trisubstituted double bond via ring closing metathesis with Grubbs' ruthenium catalyst and a site selective protection of a syn-1,2-diol. (C) 2000 Elsevier Science Ltd. All rights reserved.
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