Journal
TETRAHEDRON
Volume 56, Issue 34, Pages 6209-6217Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00580-9
Keywords
free radical cyclization; sulfonyl radical; manganese(III) acetate; aromatic amide derivatives
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Free radical cyclization reactions of alkylsulfonyl and alkylthio substituted aromatic amide derivatives are described. Carbon radicals can be generated efficiently from the sulfonyl radical induced reaction of allylsulfones or the oxidation of carbonyl compounds with manganese(III) acetate. These radicals undergo either 6-membered or 5-membered ring cyclization onto the aromatic ring effectively and provide synthetically useful methods for the syntheses of quinolinones, indolinones and indolinediones. (C) 2000 Elsevier Science Ltd. All rights reserved.
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