Journal
TETRAHEDRON
Volume 56, Issue 34, Pages 6185-6191Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00575-5
Keywords
CH/pi interaction; crystal structure; host/guest; supramolecules; CSD
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Crystal structures deposited in the Cambridge Structural Database (CSD) were examined, by use of our program CHPI, for several kinds of clarhrates in order to know the role of the CH/pi interaction in host/guest chemistry. These include cyclodextrin complexes, calix[4]arene complexes, cryptophane complexes and pseudorotaxanes. A number of short CH/pi distances have been shown in the crystal structure of these compounds. Tho result was discussed in view of the role of the CH/pi interaction in controlling the specific structure of supramolecules. (C) 2000 Elsevier Science Ltd. All rie;hts reserved.
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