Journal
PURE AND APPLIED CHEMISTRY
Volume 72, Issue 9, Pages 1635-1639Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200072091635
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A furofuran annulation/oxidative rearrangement strategy was used to construct the basic skeleton of the pyranonaphthoquinone family of antibiotics. This synthetic methodology has been applied to the synthesis of the spiroacetal-containing pyranonaphthoquinone antibiotic griseusin A, to an analog of the C-glycoside medermycin, and to a dimeric pyranonaphthoquinone.
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