Journal
ORGANIC LETTERS
Volume 2, Issue 18, Pages 2861-2863Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol006287m
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The catalytic electrophilic activation of hydrogen peroxide with transition metal compounds toward reaction with nucleophiles is a matter of very significant research and practical interest. We have now found that use of perfluorinated alcoholic solvents such as 1,1,1,3,3,3-hexafluoro-5-propanol in the absence of catalysts allowed electrophilic activation of hydrogen peroxide toward epoxidation of alkenes and the Baeyer-Villiger oxidation of ketones.
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