Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 491, Issue 1-2, Pages 78-86Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(00)00301-6
Keywords
electrodeposition; potentiostatic double-pulse; silver cluster; homogeneous distribution; nucleation
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The influence of pulse parameters of a potentiostatic double-pulse on the size distribution of silver clusters was investigated. The silver clusters were deposited from a cyanide-containing electrolyte onto indium-tin oxide electrodes. Clusters with particle diameters of 100-300 nm can be prepared on a time scale of minutes. A model is presented, which is able to explain the experimental results. (C) 2000 Elsevier Science B.V. All rights reserved.
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