Journal
ANALYTICA CHIMICA ACTA
Volume 420, Issue 2, Pages 197-203Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0003-2670(00)00891-6
Keywords
energy dispersive X-ray fluorescence; chemometry; principal component regression; matrix correction; liquid analysis
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Chemometric methods like principal component regression (PCR) are an excellent tool for the determination of matrix parameters from scattered radiation. PCR is used for the determination of carbon, hydrogen and oxygen from water and oil-based samples. This information is used in combination with fundamental parameters to determine zink in liquid samples. The method allows an accurate prediction of element concentrations in strong varying matrices. (C) 2000 Elsevier Science B.V. All rights reserved.
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